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Chapter 1 - Asymmetric Autocatalysis and the Origins of Homochirality of Organic Compounds. An Overview
Kenso Soai, Arimasa Matsumoto and Tsuneomi Kawasaki
Pages 1-30 - Book chapterAbstract only
Chapter 2 - Soai Autocatalyst as Conveyor of Chirality Coupling Autocatalysis With Asymmetric Induction
Matías Funes-Maldonado, Carlo Romagnoli, ... Mohamed Amedjkouh
Pages 31-51 - Book chapterAbstract only
Chapter 3 - Graph Theoretical and Statistical Analysis of the Impact of Soai Reaction on Natural Sciences
Béla Barabás and Ottilia Fülöp
Pages 53-69 - Book chapterAbstract only
Chapter 4 - Kinetic and Structural Aspects of Mirror-Image Symmetry Breaking in the Soai Reaction
Thomas Buhse, María E. Noble-Terán, ... Christophe Coudret
Pages 71-110 - Book chapterAbstract only
Chapter 5 - Macromolecular Versus Micromolecular World
Luciano Caglioti and Valeria Righi
Pages 111-117 - Book chapterAbstract only
Chapter 6 - The Importance of the Idea of “Parachirality” in Life Science
Noriko Fujii, Norihiko Fujii, ... Hiroaki Sakaue
Pages 119-131 - Book chapterAbstract only
Chapter 7 - Graph Theoretical Tools in Two- and Three-Dimensional Chirality Problems
Ottilia Fülöp and Béla Barabás
Pages 133-148 - Book chapterAbstract only
Chapter 8 - Synthesis of Pyrimidine-Terminated Chiral Large Molecular Architectures with Functions of Self-Replication and Self-Improvement by Asymmetric Autocatalysis
Tsuneomi Kawasaki, Arimasa Matsumoto, ... Kenso Soai
Pages 149-165 - Book chapterAbstract only
Chapter 9 - Model Equivalency in Interpreting the Stochastic Enantiomer Distribution in the Soai Reaction
Gábor Lente
Pages 167-181 - Book chapterAbstract only
Chapter 10 - Structural Study of Asymmetric Autocatalysis by X-Ray Crystallography
Arimasa Matsumoto, Tsuneomi Kawasaki and Kenso Soai
Pages 183-202 - Book chapterAbstract only
Chapter 11 - On the Relative Measures of the Degrees of Chirality and General Asymmetry
Paul G. Mezey
Pages 203-222 - Book chapterAbstract only
Chapter 12 - Asymmetric Reduction of Ketones to Chiral Platform Molecules
Bálint Fridrich, József M. Tukacs and László T. Mika
Pages 223-240 - Book chapterAbstract only
Chapter 13 - Searching for Spontaneous Mirror-Symmetry Breaking in Organoautocatalytic Reactions
Guillem Valero and Albert Moyano
Pages 241-258 - Book chapterAbstract only
Chapter 14 - Isotope Chirality in the Reagents and Intermediates of the Soai Reaction
Béla Barabás, Róbert Kurdi and Gyula Pályi
Pages 259-276 - Book chapterAbstract only
Chapter 15 - Chiral Polythiophenes
Francesca Parenti, Luisa Schenetti and Francesco Tassinari
Pages 277-297 - Book chapterAbstract only
Chapter 16 - Abiotic Emergence of Biological Homochirality
Josep M. Ribó, Joaquim Crusats, ... Albert Moyano
Pages 299-316 - Book chapterAbstract only
Chapter 17 - Catalytic Applications of Supported Ionic Liquid Phases
Csaba Fehér, Máté Papp, ... Rita Skoda-Földes
Pages 317-336 - Book chapterAbstract only
Chapter 18 - Asymmetric Autocatalysis Initiated by Crystal Chirality of Achiral Compounds
Arimasa Matsumoto, Yoshiyasu Kaimori, ... Kenso Soai
Pages 337-355 - Book chapterAbstract only
Chapter 19 - Amino Acids as Food Quality Factors in Parmigiano Reggiano Hard Cheese
Franco Bellesia, Adriano Pinetti, ... Gyula Pályi
Pages 357-367 - Book chapterNo access
Index
Pages 369-375
About the book
Description
Advances in Asymmetric Autocatalysis and Related Topics provides various viewpoints on the important developments in asymmetric autocatalysis that have occurred in the past few years, also including brand new information in the field.
Asymmetric autocatalysis is a chemical reaction which leads from achiral starting materials to chiral products, and in which the product accelerates its own formation reaction (conventional catalysis) and promotes the prevalence of its own chiral configuration (asymmetric induction). The combination of these two effects in the same reaction was unprecedented before 1995 when it was first described by Kenso SOAI at the Tokyo University of Science.
Since then, several new combinations of this effect have been found, most intriguingly the possibility of absolute asymmetric synthesis, which is the spontaneous formation of the excess of one of the enantiomers of the product, a dream of organic chemists for more than a century.
The book contains expert-contributed chapters that describe the most exciting recent developments in the field of the Soai reaction and in related topics, ranging from mechanistic studies and theoretical research, to very practical problems in chiral syntheses and products.
Advances in Asymmetric Autocatalysis and Related Topics provides various viewpoints on the important developments in asymmetric autocatalysis that have occurred in the past few years, also including brand new information in the field.
Asymmetric autocatalysis is a chemical reaction which leads from achiral starting materials to chiral products, and in which the product accelerates its own formation reaction (conventional catalysis) and promotes the prevalence of its own chiral configuration (asymmetric induction). The combination of these two effects in the same reaction was unprecedented before 1995 when it was first described by Kenso SOAI at the Tokyo University of Science.
Since then, several new combinations of this effect have been found, most intriguingly the possibility of absolute asymmetric synthesis, which is the spontaneous formation of the excess of one of the enantiomers of the product, a dream of organic chemists for more than a century.
The book contains expert-contributed chapters that describe the most exciting recent developments in the field of the Soai reaction and in related topics, ranging from mechanistic studies and theoretical research, to very practical problems in chiral syntheses and products.
Key Features
- Features contributions from global experts, including several chapters from Kenso Soai and expert colleagues
- Focuses on recent developments in the field of asymmetric autocatalysis and newly reported findings
- Explores the Soai reaction, new developments, and the light it sheds on homochirality in certain biomolecules
- Features contributions from global experts, including several chapters from Kenso Soai and expert colleagues
- Focuses on recent developments in the field of asymmetric autocatalysis and newly reported findings
- Explores the Soai reaction, new developments, and the light it sheds on homochirality in certain biomolecules
Details
ISBN
978-0-12-812824-4
Language
English
Published
2017
Copyright
Copyright © 2017 Elsevier Inc. All rights reserved.
Imprint
Academic Press