Cover for Advances in Asymmetric Autocatalysis and Related Topics

Advances in Asymmetric Autocatalysis and Related Topics

Book2017

Edited by:

Gyula Pályi, Róbert Kurdi and Claudia Zucchi

Advances in Asymmetric Autocatalysis and Related Topics

Book2017

 

Cover for Advances in Asymmetric Autocatalysis and Related Topics

Edited by:

Gyula Pályi, Róbert Kurdi and Claudia Zucchi

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Advances in Asymmetric Autocatalysis and Related Topics provides various viewpoints on the important developments in asymmetric autocatalysis that have occurred in the past few yea ... read full description

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  2. Book chapterAbstract only

    Chapter 1 - Asymmetric Autocatalysis and the Origins of Homochirality of Organic Compounds. An Overview

    Kenso Soai, Arimasa Matsumoto and Tsuneomi Kawasaki

    Pages 1-30

  3. Book chapterAbstract only

    Chapter 2 - Soai Autocatalyst as Conveyor of Chirality Coupling Autocatalysis With Asymmetric Induction

    Matías Funes-Maldonado, Carlo Romagnoli, ... Mohamed Amedjkouh

    Pages 31-51

  4. Book chapterAbstract only

    Chapter 3 - Graph Theoretical and Statistical Analysis of the Impact of Soai Reaction on Natural Sciences

    Béla Barabás and Ottilia Fülöp

    Pages 53-69

  5. Book chapterAbstract only

    Chapter 4 - Kinetic and Structural Aspects of Mirror-Image Symmetry Breaking in the Soai Reaction

    Thomas Buhse, María E. Noble-Terán, ... Christophe Coudret

    Pages 71-110

  6. Book chapterAbstract only

    Chapter 5 - Macromolecular Versus Micromolecular World

    Luciano Caglioti and Valeria Righi

    Pages 111-117

  7. Book chapterAbstract only

    Chapter 6 - The Importance of the Idea of “Parachirality” in Life Science

    Noriko Fujii, Norihiko Fujii, ... Hiroaki Sakaue

    Pages 119-131

  8. Book chapterAbstract only

    Chapter 7 - Graph Theoretical Tools in Two- and Three-Dimensional Chirality Problems

    Ottilia Fülöp and Béla Barabás

    Pages 133-148

  9. Book chapterAbstract only

    Chapter 8 - Synthesis of Pyrimidine-Terminated Chiral Large Molecular Architectures with Functions of Self-Replication and Self-Improvement by Asymmetric Autocatalysis

    Tsuneomi Kawasaki, Arimasa Matsumoto, ... Kenso Soai

    Pages 149-165

  10. Book chapterAbstract only

    Chapter 9 - Model Equivalency in Interpreting the Stochastic Enantiomer Distribution in the Soai Reaction

    Gábor Lente

    Pages 167-181

  11. Book chapterAbstract only

    Chapter 10 - Structural Study of Asymmetric Autocatalysis by X-Ray Crystallography

    Arimasa Matsumoto, Tsuneomi Kawasaki and Kenso Soai

    Pages 183-202

  12. Book chapterAbstract only

    Chapter 11 - On the Relative Measures of the Degrees of Chirality and General Asymmetry

    Paul G. Mezey

    Pages 203-222

  13. Book chapterAbstract only

    Chapter 12 - Asymmetric Reduction of Ketones to Chiral Platform Molecules

    Bálint Fridrich, József M. Tukacs and László T. Mika

    Pages 223-240

  14. Book chapterAbstract only

    Chapter 13 - Searching for Spontaneous Mirror-Symmetry Breaking in Organoautocatalytic Reactions

    Guillem Valero and Albert Moyano

    Pages 241-258

  15. Book chapterAbstract only

    Chapter 14 - Isotope Chirality in the Reagents and Intermediates of the Soai Reaction

    Béla Barabás, Róbert Kurdi and Gyula Pályi

    Pages 259-276

  16. Book chapterAbstract only

    Chapter 15 - Chiral Polythiophenes

    Francesca Parenti, Luisa Schenetti and Francesco Tassinari

    Pages 277-297

  17. Book chapterAbstract only

    Chapter 16 - Abiotic Emergence of Biological Homochirality

    Josep M. Ribó, Joaquim Crusats, ... Albert Moyano

    Pages 299-316

  18. Book chapterAbstract only

    Chapter 17 - Catalytic Applications of Supported Ionic Liquid Phases

    Csaba Fehér, Máté Papp, ... Rita Skoda-Földes

    Pages 317-336

  19. Book chapterAbstract only

    Chapter 18 - Asymmetric Autocatalysis Initiated by Crystal Chirality of Achiral Compounds

    Arimasa Matsumoto, Yoshiyasu Kaimori, ... Kenso Soai

    Pages 337-355

  20. Book chapterAbstract only

    Chapter 19 - Amino Acids as Food Quality Factors in Parmigiano Reggiano Hard Cheese

    Franco Bellesia, Adriano Pinetti, ... Gyula Pályi

    Pages 357-367

  21. Book chapterNo access

    Index

    Pages 369-375

About the book

Description

Advances in Asymmetric Autocatalysis and Related Topics provides various viewpoints on the important developments in asymmetric autocatalysis that have occurred in the past few years, also including brand new information in the field.

Asymmetric autocatalysis is a chemical reaction which leads from achiral starting materials to chiral products, and in which the product accelerates its own formation reaction (conventional catalysis) and promotes the prevalence of its own chiral configuration (asymmetric induction). The combination of these two effects in the same reaction was unprecedented before 1995 when it was first described by Kenso SOAI at the Tokyo University of Science.

Since then, several new combinations of this effect have been found, most intriguingly the possibility of absolute asymmetric synthesis, which is the spontaneous formation of the excess of one of the enantiomers of the product, a dream of organic chemists for more than a century.

The book contains expert-contributed chapters that describe the most exciting recent developments in the field of the Soai reaction and in related topics, ranging from mechanistic studies and theoretical research, to very practical problems in chiral syntheses and products.

Advances in Asymmetric Autocatalysis and Related Topics provides various viewpoints on the important developments in asymmetric autocatalysis that have occurred in the past few years, also including brand new information in the field.

Asymmetric autocatalysis is a chemical reaction which leads from achiral starting materials to chiral products, and in which the product accelerates its own formation reaction (conventional catalysis) and promotes the prevalence of its own chiral configuration (asymmetric induction). The combination of these two effects in the same reaction was unprecedented before 1995 when it was first described by Kenso SOAI at the Tokyo University of Science.

Since then, several new combinations of this effect have been found, most intriguingly the possibility of absolute asymmetric synthesis, which is the spontaneous formation of the excess of one of the enantiomers of the product, a dream of organic chemists for more than a century.

The book contains expert-contributed chapters that describe the most exciting recent developments in the field of the Soai reaction and in related topics, ranging from mechanistic studies and theoretical research, to very practical problems in chiral syntheses and products.

Key Features

  • Features contributions from global experts, including several chapters from Kenso Soai and expert colleagues
  • Focuses on recent developments in the field of asymmetric autocatalysis and newly reported findings
  • Explores the Soai reaction, new developments, and the light it sheds on homochirality in certain biomolecules
  • Features contributions from global experts, including several chapters from Kenso Soai and expert colleagues
  • Focuses on recent developments in the field of asymmetric autocatalysis and newly reported findings
  • Explores the Soai reaction, new developments, and the light it sheds on homochirality in certain biomolecules

Details

ISBN

978-0-12-812824-4

Language

English

Published

2017

Copyright

Copyright © 2017 Elsevier Inc. All rights reserved.

Imprint

Academic Press

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Editors

Gyula Pályi

University of Modena and Reggio Emilia, Modena, Italy

Róbert Kurdi

University of Pannonia, Veszprém, Hungary

Claudia Zucchi

University of Modena and Reggio Emilia, Modena, Italy